32; Oxygen bridged bimetallic CuMoO4 nanocatalyst for benzylic alcohol oxidation; mechanism and DFT study; A. J. Org. Chem. 2021; DOI: 10.1002/ajoc.202100192 (In Press)
P. K. Behera, P. Choudhury, S K. Sahu, R. R. Sahu, A. N. Harvat, C. McNulty, A. Stitgen, J. Scanlon, M. Kar, and Prof. L. Rout
31 Dehydrogenative oxidation of aryl methanol using oxygen bridged [Cu-O-Se] bimetallic catalyst New. J. Chem, 2021 https://doi.org/10.1039/D1NJ00712B
P. Choudhury, P. K. Behera, S. K. Sahu, T. Bisoyi, R. R. Sahu, S. R. Prusty, A. Stitgen, J. Scanlon, Prof. L. Rout,*
1: Synthesis of Acyl Derivatives of Cotarnine, Org. Syn, 2018, 95, 455. DOI: 10.15227/orgsyn.095.0455
Dr. Laxmidhar Rout, B. B. Parida, G. Phaomei, B.Emmanuel, and Prof.A. K. Sahoo,
2: Recent Advances in Copper-Catalyzed Oxidation of Organic Compounds. Coord. Chem. Rev.2008, 252, 134.
T. Punniyamurthy and L. Rout, https://doi.org/10.1016/j.ccr.2007.04.003
Abstract: The copper-catalyzed oxidation of organic compounds has made considerable progress in the recent years. Molecular oxygen, aqueous hydrogen peroxide, tert-butyl hydroperoxide and peroxyesters have been employed as terminal oxidants for this purpose. The use of polymer and solid-supported catalysts, ionic liquids and fluorous biphase systems (FBS) has been demonstrated to facilitate the recyclability of the catalysts. Efforts have been made for the aqueous oxidation processes employing water-soluble copper complexes. Chiral catalysts have been designed and developed for the enantioselective oxidative coupling of 2-naphthols, Baeyer–Villiger oxidation and Kharasch–Sosnovsky reaction with high enantioselectivity.
L. Rout and T. Punniyamurthy, https://doi.org/10.1002/adsc.200600397
Abstrcat: The oxidation of alcohols to aldehydes and ketones has been described using silica-supported vanadium(iv) oxide (V/SiO2, 1) in the presence of tert-butyl hydroperoxide in tert-butyl alcohol at ambient temperature with quantitative yields. The procedure is simple, efficient and environmentally benign.
L. Rout and T. Punniyamurthy, https://doi.org/10.1002/adsc.200505166
Abstrcat: A recyclable silica supported vanadium 1 catalyzes the oxidation of tertiray amines to the corresponding N-oxides with 30% H2O2 in high yield